Diffusion of Ions Between Two Solutions Saturated With Respect to Hydroxyapatite: A Possible Mechanism for Subsurface Demineralization of Teeth
نویسنده
چکیده
Diffusion-controlled dissolution and precipitation reactions occur in many biological systems and some non-stirred in vitro systems. Previous studies have shown that differences in the diffusion rates of the ions involved in a dissolution/precipitation reaction can produce significant effects on the rate and course of the reaction. We report here results of a study that show inter-diffusion of ions between two solutions, both saturated with respect to hydroxyapatite but with dissimilar compositions, resulted in one solution becoming undersaturated and the other supersaturated. A model is proposed that may explain the formation of a mineral-dense layer in the caries process.
منابع مشابه
Diffusion Controlled Dissolution and Precipitation*
Dissolution and precipitation reactions that occur in biological systems and in non-stirred in vitro systems generally are diffusion-controlled. Subsurface demineralization of tooth enamel in dental caries, which has been the subject of considerable interest, is an example of such processes. In the caries process ions from solubilized tooth mineral, i. e., Ca, P04, and OH, need to be transporte...
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